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4-aminobenzoic acid

From Crystal growing


   4-aminobenzoic acid   
Names: 4-aminobenzoic acid
para-aminobenzoic acid
vitamin B10
PABA
Formula: NH2C6H4COOH
Molar mass: 137.138 g/mol
Density: 1.374 g/cm3 (α-form)
1.39 g/cm3 (β-form)
1.43 g/cm3 (γ-form)
1.48 g/cm3 (δ-form)
Crystal system: monoclinic (α-form)
a=18.571 Å, b=3.843 Å, c=18.632 Åα=90°, β=93.67°, γ=90°
monoclinic (β-form)
a=6.278 Å, b=8.583 Å, c=12.365 Åα=90°, β=100.13°, γ=90°
cubic (γ-form)
a=26.9945 Å, b=26.9945 Å, c=26.9945 Åα=90°, β=90°, γ=90°
monoclinic (δ-form)
a=6.4341 Å, b=4.6151 Å, c=10.5313 Åα=90°, β=100.73°, γ=90°
Shapes:
https://en.crystalls.info/w/uploads/media/5/52/Needle.json

Color: white
Melting point: 187 °C460.15 K <br />368.6 °F <br />828.27 °R <br />
Stability: stable
Hardness: fragile
Toxicity: slightly toxic
LD50=1000mg/kg

Description

Organic compound, monobasic aromatic aminoacid. Doesn't form water hydrates.

Can be bought in pharmacy (as vitamin B10 - in form of pills).

Influence of temperature

Due to low solubility in water, it's easier to grow crystals by cooling the solution.

Can be easily separated from insoluble impurities containing in the pharmacy pills by dissolving in hot water and filtration.

Temperatureg/100,00 g waterg/100,00 g ethanolg/100,00 g diethyl etherg/100,00 g benzeneg/100,00 g dioxaneg/100,00 g 1-butanol
18°C291.15 K <br />64.4 °F <br />524.07 °R <br />0.495
20°C293.15 K <br />68 °F <br />527.67 °R <br />122
25°C298.15 K <br />77 °F <br />536.67 °R <br />0.50.0711.716
30°C303.15 K <br />86 °F <br />545.67 °R <br />0.6110.35
37°C310.15 K <br />98.6 °F <br />558.27 °R <br />0.84
Soluble in ethyl acetate. Slightly soluble in benzylamine and 1-butylamine. Insoluble in dibutylamine, dipropylamine and diethylamine.



Sources