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Ammonium pentachloroferrate (III)

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   Ammonium pentachloroferrate(III)   
Names: ammonium pentachloroferrate
diammonium pentachloroferrate
ammonium ferrichloride
Formula: (NH4)2[FeCl5(H2O)] (anhydrous)
(NH4)2[FeCl5(H2O)] · H2O (monohydrate)
Molar mass: 287.202 g/mol (anhydrous)
305.217 g/mol (monohydrate)
Crystal system: orthorhombic (monohydrate)
a=13.706 Å, b=9.924 Å, c=7.024 Åα=90°, β=90°, γ=90°
Shapes:
https://en.crystalls.info/w/uploads/media/9/97/Truncated_oblique_rhombic_prism.json
Truncated oblique rhombic prism

Color: red-brown
Decomposition point: 87 °C360.15 K <br />188.6 °F <br />648.27 °R <br /> (tetrahydrate)
Electricity properties: ferroelectric
Magnetic properties: antiferromagnetic
Stability: slowly erodes (monohydrate)
hygroscopic (anhydrous)
Hardness: fragile
Toxicity: slightly toxic

Description

Inorganic complex compound, salt of ammonium ion and complex pentachloroferrate ion. From water solutions crystallizes as monohydrate.

Precursors

Reaction between ammonium and iron(III) chlorides

Chemical equation:

2NH4Cl + FeCl3 + H2O = (NH4)2[FeCl5(H2O)]


For preparation of 100.00g of ammonium pentachloroferrate(III) monohydrate а 35.05g of chloride ammonium and 88.56g of chloride iron(III) hexahydrate is required.

Dissolve compounds in hot water apart and then mix solutions into one container with intense stirring. Cooling or evaporation of a solution will cause double salt crystallyzation.

Influence of temperature

Grow at room temperature. Heating of solution leads to iron(III) chloride hydrolysis.

Storage conditions

Store in its original form or under several layers of varnish at average humidity and room temperature. Do not store in matchboxes or cotton wool and do not heat.

Solubility

Highly soluble in water.


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   Chlorides
Salts

Ammonium chloride (NH4Cl) • Barium chloride (BaCl2) • Calcium chloride (CaCl2) • Cadmium chloride (CdCl2) • Cobalt(II) chloride (CoCl2) • Copper(II) chloride (CuCl2) • Iron(II) chloride (FeCl2) • Iron(III) chloride (FeCl3) • Lead(II) chloride (PbCl) • Manganese(II) chloride (MnCl2) • Potassium chloride (KCl) • Sodium chloride (NaCl) • Strontium chloride (SrCl2) • Tin(II) chloride (SnCl2) • Zirconyl chloride (ZrOCl2)

Double salts

Rubidium-gold(III)-palladium(II) chloride (2RbCl · AuCl3 · PdCl2)

Adducts

Diglycine hydrochloride (2NH2CH2COOH · HCl) • Glutamic acid hydrochloride (C5H9NO4 · HCl) • Glucose and sodium chloride complex (2C6H12O6 · NaCl) • Hydroxylammonium chloride (NH2OH · HCl) • P-nitroaniline hydrochloride (C6H6N2O2 · HCl) • Urea and sodium chloride complex (CO(NH4)2 · NaCl)

Complexes

Ammonium pentachloroferrate(III) ((NH4)2[FeCl5]) • Ammonium tetrachlorocuprate(II) ((NH4)2[CuCl4]) • Lithium trioxalatoferrate(III)-chloride (Li4[Fe(C2O4)3]Cl) • Hexamminecobalt(III) chloride ([Co(NH3)6]Cl2) • Hexaamminenickel chloride ([Ni(NH3)6]Cl2) • Potassium hexachlororhodate(III) (K3[RhCl6])


   Ammonium compounds
Salts

Ammonium citrate ((NH4)3C3H5O(COO)3) • Ammonium chloride (NH4Cl) • Ammonium dichromate ((NH4)2Cr2O7) • Ammonium dihydrophosphate (NH4H2PO4) • Ammonium nitrate (NH4NO3) • Ammonium perrhenate (NH4ReO4) • Ammonium sulfate ((NH4)2SO4) • Ammonium succinate ((NH4)2C4H4O4) • Ammonium tetraborate ((NH4)2B4O7) • Ammonium thiocyanate (NH4NCS)

Double salts

Aluminum-ammonium sulfate (NH4Al(SO4)2) • Calcium-ammonium nitrate (5Ca(NO3)2 · NH4NO3) • Chromium(III)-ammonium sulfate (NH4Cr(SO4)2) • Cobalt(II)-ammonium sulfate ((NH4)2Co(SO4)2) • Copper(II)-ammonium sulfate ((NH4)2Cu(SO4)2) • Iron(II)-ammonium sulfate ((NH4)2Fe(SO4)2) • Iron(III)-ammonium sulfate (NH4Fe(SO4)2) • Magnesium-ammonium sulfate ((NH4)2Mg(SO4)2) • Manganese(II)-ammonium sulfate ((NH4)2Mn(SO4)2) • Nickel-ammonium sulfate ((NH4)2Ni(SO4)2) • Sodium-ammonium sulfate (NaNH4SO4) • Vanadium(III)-ammonium sulfate (NH4V(SO4)2) • Zinc-ammonium sulfate ((NH4)2Zn(SO4)2)

Complexes

Ammines • Ammonium dioxalatocuprate(II) ((NH4)2[Cu(C2O4)2]) • Ammonium pentachloroferrate(III) ((NH4)2[FeCl5]) • Ammonium tetrachlorocuprate(II) ((NH4)2[CuCl4]) • Ammonium trioxalatoferrate(III) ((NH4)3[Fe(C2O4)3])


   Iron compounds
Salts

Iron (Fe) • Iron(II) acetate (Fe(CH3COO)2) • Iron(II) chloride (FeCl2) • Iron(III) chloride (FeCl3) • Iron(II) citrate (FeHC3H5O(COO)3) • Iron(II) formate (Fe(COOH)2) • Iron(III) formate (Fe2(COOH)3) • Iron(II) nitrate (Fe(NO3)2) • Iron(II) phosphate (Fe3(PO4)2) • Iron(II) sulfate (FeSO4) • Iron(III) sulfate (Fe2(SO4)3)

Double salts

Iron(III)-ammonium sulfate ((NH4)Fe(SO4)2) • Iron(II)-ammonium sulfate ((NH4)2Fe(SO4)2) • Iron(II)-potassium sulfate (K2Fe(SO4)2) • Iron(II)-magnesium sulfate ((Fe,Mg)SO4) • Copper(II)-iron(II) sulfate ((Cu,Fe)SO4)

Complexes


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