Glucose and sodium chloride adduct

Glucose and sodium chloride adduct ;
Names:	adduct of glucose and sodium chloride; complex of glucose and sodium chloride;
Formula:	2C6H12O6 · NaCl (anhydrous); 2C6H12O6 · NaCl · H2O (monohydrate);
Molar mass:	418.754 g/mol (anhydrous); 436.768 g/mol (monohydrate);
Crystal system:	hexagonal (monohydrate); a=16.836 Å, b=16.836 Å, c=17.013 Åα=90°, β=90°, γ=120°;
Shapes:	Template:Rhombohedron https://en.crystalls.info/w/uploads/media/7/7b/Beveled_rhombic_prism.json Beveled rhombic prism https://en.crystalls.info/w/uploads/media/f/fd/Beveled_truncated_rhombic_prism.json Beveled truncated rhombic prism https://en.crystalls.info/w/uploads/media/c/c4/Hexagonal_bipyramid.json Hexagonal bipyramid ;
Color:	colorless;
Stability:	stable (monohydrate)

Description

Organic compound, adduct of glucose an sodium chloride. From water solutions crystallizes as monohydrate.

Precursors

Reaction between glucose and sodium chloride

Chemical equation:

2C₆H₁₂O₆ + NaCl = 2C₆H₁₂O₆ · NaCl

For preparation of 100.00g of glucose and sodium chloride adduct

monohydratemonohydrate
anhydrous

а 82.49g of glucose and 13.38g of sodium chloride is required.

Dissolve compounds in hot water apart and then mix solutions into one container with intense stirring. Cooling or evaporation of a solution will cause double salt crystallyzation.

Notes

Due to high solubility and high solution viscosity, each particle of dust makes a crystallization center, forming a large number of small crystals. To get large monocrystals, it is recommended to cover a container with the solution with cardboard or parer, with small hole in it to ensure slow water evaporation.
Fast growth produces crystals with shape of elongated bipyramid. Slow growth produces crystals with shape of rhomrohedron and beveled prisms.

Storage conditions

Keep in its original form or under several layers of varnish at average humidity and room temperature. Do not keep crystals near heaters.

Solubility

TableGraph

Temperature	g/`100,00` g water
25°C298.15 K <br />77 °F <br />536.67 °R <br />	`~90`

Gallery

Video

Sources

Chlorides
Salts	Ammonium chloride (NH₄Cl) • Barium chloride (BaCl₂) • Calcium chloride (CaCl₂) • Cadmium chloride (CdCl₂) • Cobalt(II) chloride (CoCl₂) • Copper(II) chloride (CuCl₂) • Iron(II) chloride (FeCl₂) • Iron(III) chloride (FeCl₃) • Lead(II) chloride (PbCl) • Manganese(II) chloride (MnCl₂) • Potassium chloride (KCl) • Sodium chloride (NaCl) • Strontium chloride (SrCl₂) • Tin(II) chloride (SnCl₂) • Zirconyl chloride (ZrOCl₂)
Double salts	Rubidium-gold(III)-palladium(II) chloride (2RbCl · AuCl₃ · PdCl₂)
Adducts	Diglycine hydrochloride (2NH₂CH₂COOH · HCl) • Glutamic acid hydrochloride (C₅H₉NO₄ · HCl) • Glucose and sodium chloride adduct (2C₆H₁₂O₆ · NaCl) • Hydroxylammonium chloride (NH₂OH · HCl) • P-nitroaniline hydrochloride (C₆H₆N₂O₂ · HCl) • Urea and sodium chloride adduct (CO(NH₄)₂ · NaCl)
Complexes	Ammonium pentachloroferrate(III) ((NH₄)₂[FeCl₅]) • Ammonium tetrachlorocuprate(II) ((NH₄)₂[CuCl₄]) • Lithium trioxalatoferrate(III)-chloride (Li₄[Fe(C₂O₄)₃]Cl) • Hexamminecobalt(III) chloride ([Co(NH₃)₆]Cl₂) • Hexaamminenickel chloride ([Ni(NH₃)₆]Cl₂) • Potassium hexachlororhodate(III) (K₃[RhCl₆])

Sodium compounds
Salts	Sodium acetate (NaCH₃COO) • Sodium bromide (NaBr) • Sodium citrate (Na₃C₃H₅O(COO)₃) • Sodium chlorate (NaClO₃) • Sodium chloride (NaCl) • Sodium cyclamate (C₆H₁₂NNaO₃S) • Sodium decavanadate (Na₆V₁₀O₂₈) • Sodium ethilate (NaC₂H₅O) • Sodium glutamate (NaC₅H₈NO₄) • Sodium hydrocarbonate (NaHCO₃) • Sodium hydrosulfate (NaHSO₄) • Sodium iodide (NaI) • Sodium metavanadate (NaVO₃) • Sodium niobate (NaNbO₃) • Sodium nitrate (NaNO₃) • Sodium oxalate (Na₂C₂O₄) • Sodium para-aminosalicylate (C₇H₆NNaO₃) • Sodium perchlorate (NaClO₄) • Sodium saccharinate (C₇H₄NaNO₃S) • Sodium sulfate (Na₂SO₄) • Sodium sulfide (Na₂S) • Sodium tetraborate (Na₂B₄O₇) • Sodium thiosulfate (Na₂S₂O₃) • Sodium trichloroacetate (NaCCl₃COO) • Sodium trioxalatoaluminate (Na₃[Al(C₂O₄)₃]) • Sodium tungstate (Na₂WO₄)
Double salts	Potassium-sodium tartrate (KNaC₄H₄O₆) • Sodium-ammonium sulfate (NaNH₄SO₄) • Uranyl-sodium acetate (NaUО2(CH₃COO)₃) • Uranyl-zinc-sodium acetate (NaZn(UO₂)₃(CH₃COO)₉) • Zinc-sodium sulfate (Na₂Zn(SO₄)₂)
Adducts	Glucose and sodium bromide adduct (2C₆H₁₂O₆ · NaBr) • Glucose and sodium chloride adduct (2C₆H₁₂O₆ · NaCl) • Urea and sodium chloride adduct (CO(NH₄)₂ · NaCl)
Complex compounds	Sodium dicarbonatocuprate(II) (Na₂[Cu(CO₃)₂]) • Sodium dioxalatocuprate(II) (Na₂[Cu(C₂O₄)₂]) • Sodium ethylenediaminetetraacetate-ferrate(III) (Na[Fe((OOCCH₂)₂N(CH₂)₂N(CH₂COO)₂)]) • Sodium hexacyanoferrate(II) (Na₄[Fe(CN)₆]) • Tripotassium-sodium hexacyanoferrate(II) (K₃Na[Fe(CN)₆]) • Sodium hexafluorosilicate (Na₂[SiF₆]) • Sodium nitroprusside (Na₂[Fe(CN)₅NO]) • Sodium trioxalatochromate(III) (Ns₃[Cr(C₂O₄)₃]) • Dipotassium-sodium trioxalatoferrate(III) (K₂Na[Fe(C₂O₄)₃]) • Potassium-sodium trioxalatoferrate(III) (K₅Na[Fe(C₂O₄)₃]₂) • Sodium trioxalatoferrate(III) (Na₃[Fe(C₂O₄)₃])

Adducts

Diglycine hydrochloride (2NH₂CH₂COOH · HCl) • Glucose and sodium bromide adduct (2C₆H₁₂O₆ · NaBr) • Glucose and sodium chloride adduct (2C₆H₁₂O₆ · NaCl) • Glutamic acid hydrochloride (C₅H₉NO₄ · HCl) • Glutamic acid sulfate (C₅H₉NO₄ · H₂SO₄) • Hydroxylammonium chloride (NH₂OH · HCl) • P-nitroaniline hydrochloride (C₆H₆N₂O₂ · HCl) • Urea and sodium chloride adduct (CO(NH₄)₂ · NaCl) • Copper(II) formate and urea adduct (Cu(HCOO)₂ · 2CO(NH₂)₂) • Urea citrate ((NH₂)₂CO · C₆H₈O₇)

Glucose and sodium chloride adduct
Names:	adduct of glucose and sodium chloride complex of glucose and sodium chloride
Formula:	2C₆H₁₂O₆ · NaCl (anhydrous) 2C₆H₁₂O₆ · NaCl · H₂O (monohydrate)
Molar mass:	418.754 g/mol (anhydrous) 436.768 g/mol (monohydrate)
Crystal system:	hexagonal (monohydrate) a=16.836 Å, b=16.836 Å, c=17.013 Åα=90°, β=90°, γ=120°
Shapes:	Template:Rhombohedron Beveled rhombic prism Beveled truncated rhombic prism Hexagonal bipyramid
Color:	colorless
Stability:	stable (monohydrate)