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Nitratopentakis-tiokarbamatbismuth(III) nitrate

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   Nitratopentakis-tiokarbamatbismuth(III) nitrate   
Names: nitratopentakis-tiokarbamatbismuth(III) nitrate
thiokarbamatbismuth(III) nitrate
Formula: [Bi(NO3)(CS(NH2)2)5](NO3)2 (anhydrous)
[Bi(NO3)(CS(NH2)2)5](NO3)2 · H2O (monohydrate)
Molar mass: 775.601 g/mol (anhydrous)
793.616 g/mol (monohydrate)
Crystal system: triclinic (monohydrate)
a=9.292 Å, b=9.788 Å, c=14.0017 Åα=80.667°, β=84.033°, γ=86.28°
Shapes:
https://en.crystalls.info/w/uploads/media/7/71/Oblique_hexagonal_prism.json
Oblique hexagonal prism
https://en.crystalls.info/w/uploads/media/4/4f/Deformed_oblique_hexagonal_prism.json
Deformed oblique hexagonal prism

Color: dark-red
Magnetic properties: diamagnetic
Stability: stable (anhydrous)
Hardness: relatively strong
Toxicity: poisonous

Description

Inorganic compound, complex compound transitional metal bismuth, organic compound thiourea and inorganic nitric acid. From water solutions crystallizes as monohydrate.

Precursors

Reaction between bismuth(III) nitrate and thiourea

Chemical equation:

Bi(NO3)3 + 5CS(NH2)2 = [Bi(NO3)(CS(NH2)2)5](NO3)2


For preparation of 100.00g of nitratopentakis-tiokarbamatbismuth(III) nitrate monohydrate а 61.12g of bismuth(III) nitrate pentahydrate and 47.96g of thiourea is required.

Add to the flask with thiourea solution a bismuth(III) nitrate solution with stirring. After reaction will stop, filter the solution and use it for crystal growing.

Notes

The solution is hydrolyzed with hydrogen sulphide emission after few weeks.

Storage conditions

Keep in its original form or under several layers of varnish at average humidity and room temperature. Do not keep crystals near heaters.

Solubility

Soluble in water.



Sources



   Nitrates
Salts

Ammonium nitrate (NH4NO3) • Barium nitrate (Ba(NO3)2) • Bismuth(III) nitrate (BI(NO3)3) • Calcium nitrate (Ca(NO3)2) • Cesium nitrate (CsNO3) • Cobalt(II) nitrate (Co(NO3)2) • Copper(II) nitrate (Cu(NO3)2) • Iron(II) nitrate (Fe(NO3)2) • Lead(II) nitrate (Pb(NO3)2) • Neodymium nitrate (Nd(NO3)3) • Nickel nitrate (Ni(NO3)2) • Potassium nitrate (KNO3) • Silver(I) nitrate (AgNO3) • Sodium nitrate (NaNO3) • Strontium nitrate (Sr(NO3)2) • Uranyl nitrate (UO2(NO3)2) • Zirconyl nitrate (ZrO(NO3)2)

Double salts

Calcium-ammonium nitrate (5Ca(NO3)2 · NH4NO3) • Cerium(IV)-ammomium nitrate (2NH4NO3 · Ce(NO3)4) • Cerium(III)-cobalt nitrate (3Co(NO3)2 · 2Ce(NO3)3) • Cerium(III)-cobalt-manganese nitrate (3(Co,Mn)(NO3)2 · 2Ce(NO3)3) • Cerium(III)-manganese nitrate (3Mn(NO3)2 · 2Ce(NO3)3)

Complexes

Bis-thetramethylethylenediaminecopper(II) nitrate ([Cu((H3CNCH3)2C4H8)](NO3)2) • Nitratopentakis-karbamatbismuth(III) nitrate ([Bi(NO3)(CO(NH2)2)5](NO3)2) • Nitratopentakis-tiokarbamatbismuth(III) nitrate ([Bi(NO3)(CS(NH2)2)5](NO3)2)



   Bismuth compounds
Salts

Bismuth (Bi) • Bismuth(III) nitrate (Bi(NO3)3)

Complexes

Nitratopentakis-tiokarbamatbismuth(III) nitrate ([Bi(NO3)(CS(NH2)2)5](NO3)2) • Potassium tetraiodobismuthate (К[BiI4])


   Thiourea compounds

Nitratopentakis-tiokarbamatbismuth(III) nitrate ([Bi(NO3)(CS(NH2)2)5](NO3)2) • Thiourea ((NH2)2CO)


   Complex compounds
Salts

Bis-thetramethylethylenediaminecopper(II) nitrate ([Cu((H3CNCH3)2C4H8)](NO3)2) • Cerium(III) sulfocerate(IV) (Ce4[Ce(SO4)4]3) • Glycinecopper(II) sulfate ([Cu(NH2CH2COOH)]SO4) • Hexakarbamatzinc sulfate ([(CON2H4)6Zn]SO4) • Nitratopentakis-karbamatbismuth(III) nitrate ([Bi(NO3)(CO(NH2)2)5](NO3)2) • Nitratopentakis-tiokarbamatbismuth(III) nitrate ([Bi(NO3)(CS(NH2)2)5](NO3)2) • Potassium tetraiodobismuthate (К[BiI4]) • Potassium tetraiodomercurate(II) (K2[HgI4]) • Sodium ethylenediaminetetraacetate-ferrate(III) (Na[Fe((OOCCH2)2N(CH2)2N(CH2COO)2)]) • Tris(ethylenediamine)nickel(II) oxalate ([Ni(H2NCH2CH2NH2)3]C2O4) • Tris(hydroxymethil)methanoaminecopper(II) sulfate ([Cu(NH2C(CH2OH)3)4]SO4)

Categories

Adducts‎‎ • Ammines • Dicarbonatocuprates • Dioxalatocuprates • Heptafluorzirconates • Hexachlororhodates • Hexacyanochromates • Hexacyanocobaltates • Hexacyanoferrates • Hexanitrocobaltates • Nitroprussides • Pentachloroferrates • Tetrachlorocuprates • Trioxalatoaluminates • Trioxalatochromates • Trioxalatoferrates

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